Yes there is a card spacer to keep the plate surface of the the cover glass, these were simple 1 ply card in depth or more elaborate and up to a 1/4 inch in depth and cover with gold painted paper (for a look at these see the passe partout gallery in the technology galleries section).
The main trick with passe partout (and its not easy) is being able to paint a thin line consistently (so aesthetically this enhances the framing effect, not detracting with an inconsistent one) and in having a good edge to the line/mat window edge. Not to blow my own horn but Grant Romer of the Eastman House and photo conservation fame, has said that CasedImage.com’s are the best, if not the only ones in modern times to emulate the nineteenth century examples.
Bar a couple of trade secrets I am happy to give advice about making passe partout ( and dag enclosures in general) and would urge you to have a go and ask more questions here. observing fine dag enclosures and making them are two different things and much of the learning is in the making. As far as I know there is no historical record of methods used, unlike as with cases in E Anthony’s catalogue of 1854.