I am going to back track a little bit. I have been obsessing recently about gilding, and rereading the old manuals it appears that chloroauric acid is what was used and recommended in the 19th century, not gold (III) chloride. Most of the manuals provide instructions on making your own gold chloride, and the instructions all suggest using aqua regia, which would produce chloroauric acid. Any disagreement? I know there are a few folks who are currently buffering their chloroauric acid with sodium carbonate or sodium metaborate to produce a more neutral solution, in line with the pH of gold (III) chloride.
As an aside, why do we age our gilding solution? None of the old manuals say anything about aging it, although one mentions that it should become “limpid.”
Such are the dangers of reading…