Daguerreotypes Without Mercury.

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  • #7488
    RichardCynan
    Participant

    Found in Humphrey’s American Hand Book of the Daguerreotype.

    Does it work? Has it ever been attempted? There’s no mention of red light, just heat/darkness.

    Sounds too good to be true…

    DAGUERREOTYPES WITHOUT MERCURY.

    The following process possesses some interest, and is

    worthy a trial from operators. M. Natterer, of Vienna,

    discovered a process for obtaining proofs on iodized plates

    with the chloride of sulphur, without the use of mercury.

    A plate of silver is iodized in the usual manner, and then placed

    on the top of a vessel six or eight inches high, having at

    the bottom, in a small cup, a few drops of chloride of sulphur;

    it should remain exposed to the action of the vapor until

    the sombre yellow color is changed to a red, after which it

    is brought to a focus m the camera, where it is exposed

    to the light in the camera, for about the time necessary

    to produce an ordinary daguerreotype. The plate is then taken

    out and examined in the camera by the light of a candle.

    It often occurs that no trace of the image is as yet perceptible,

    but if the plate is heated by placing over a spirit lamp

    the unprepared side, or if left for some time in the dark,

    or, lastly, if exposed only a few seconds to a weak, dimmed light,

    the positive picture then appears with all its shades.

    Of these three modes of bringing out the image, the second

    is superior to the others.

    #7987
    photolytic
    Participant

    This is not the first mention of Daguerreotypes without mercury on this forum.

    I call your attention to a portion of a PDF of mine on heliochromes posted by John Lewis 7 months ago.

     

    They were made by coating silver plates for 3 minutes in 3.0 or 4.5% FeCl3 solutions which also

    contained 2.2 or 2.6% CuSO4 respectively followed by a 5 second rinse in distilled water. Longer

    contacts with water both before and after exposure were avoided.

    These plates were exposed through a color transparency until a muted color image was visible.

    When these plates were fixed in a solution of sodium thiosulfate, the colors completely disappeared, leaving behind a B&W Daguerreotype image, produced not only without mercury but without nasty iodine bromine or chlorine fumes.

     

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